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Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system

Weilong WANG, Yukun HU, Jinyue YAN, Jenny NYSTR?M, Erik DAHLQUIST

《能源前沿（英文）》 2010年 第4卷 第4期   页码 469-474 doi: 10.1007/s11708-010-0123-9

摘要： Energy consumption for space and tap water heating in residential and service sectors accounts for one third of the total energy utilization in Sweden. District heating (DH) is used to supply heat to areas with high energy demand. However, there are still detached houses and sparse areas that are not connected to a DH network. In such areas, electrical heating or oil/pellet boilers are used to meet the heat demand. Extending the existing DH network to those spare areas is not economically feasible because of the small heat demand and the large investment required for the expansion. The mobilized thermal energy storage (M-TES) system is an alternative source of heat for detached buildings or sparse areas using industrial heat. In this paper, the integration of a combined heat and power (CHP) plant and an M-TES system is analyzed. Furthermore, the impacts of four options of the integrated system are discussed, including the power and heat output in the CHP plant. The performance of the M-TES system is likewise discussed.

关键词： Mobilized thermal energy system     district heating     thermal energy storage     combined heat and power     detached houses    

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Experimental study and assessment of thermal energy storage mortar with paraffin/recycled brick powder

Luchen HAO; Jianzhuang XIAO; Wanzhi CAO; Jingting SUN

《结构与土木工程前沿（英文）》 2022年 第16卷 第10期   页码 1301-1314 doi: 10.1007/s11709-022-0883-4

摘要： Thermal energy storage recycled powder mortar (TESRM) was developed in this study by incorporating paraffin/recycled brick powder (paraffin/BP) composite phase change materials (PCM). Fourier transform infrared and thermogravimetric analysis results showed that paraffin/BP composite PCM had good chemical and thermal stability. The onset melting temperature and latent heat of the composite PCM were 46.49 °C and 30.1 J·g−1. The fresh mortar properties and hardened properties were also investigated in this study. Paraffin/BP composite PCM with replacement ratio of 0%, 10%, 20%, and 30% by weight of cement were studied. The results showed that the static and dynamic yield stresses of TESRM were 699.4% and 172.9% higher than those of normal mortar, respectively. The addition of paraffin/BP composite PCM had a positive impact on the mechanical properties of mortar at later ages, and could also reduce the dry shrinkage of mortar. The dry shrinkage of TESRM had a maximum reduction about 26.15% at 120 d. The thermal properties of TESRM were better than those of normal mortar. The thermal conductivity of TESRM was 36.3% less than that of normal mortar and the heating test results showed that TESRM had good thermal energy storage performance.

关键词： recycled powder mortar     recycled brick powder     thermal energy storage     paraffin     phase change material    

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Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1038-1050 doi: 10.1007/s11705-022-2279-3

摘要： Phase change materials are potential candidates for the application of latent heat storage. Herein, we fabricated porous capsules as shape-stable materials from cellulose-based polyelectrolyte complex, which were first prepared using cellulose 6-(N-pyridinium)hexanoyl ester as the cationic polyelectrolyte and carboxymethyl cellulose as the anionic polyelectrolyte to encapsulate polyethylene glycol by the vacuum impregnation method. Furthermore, the multi-walled carbon nanotube or graphene oxide, which were separately composited into the polyelectrolytes complex capsules to enhance thermal conductivity and light-to-thermal conversion efficiency. These capsules owned a typical core–shell structure, with an extremely high polyethylene glycol loading up to 34.33 g∙g‒1. After loading of polyethylene glycol, the resulted cellulose-based composite phase change materials exhibited high thermal energy storage ability with the latent heat up to 142.2 J∙g‒1, which was 98.5% of pure polyethylene glycol. Further results showed that the composite phase change materials demonstrated good form-stable property and thermal stability. Moreover, studies involving light-to-thermal conversion determined that composite phase change materials exhibited outstanding light-to-thermal conversion performance. Considering their exceptional comprehensive features, innovative composite phase change materials generated from cellulose presented a highly interesting choice for thermal management and renewable thermal energy storage.

关键词： cellulose     polyelectrolytes     phase change materials     thermal energy storage     light-to-thermal conversion    

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A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

《能源前沿（英文）》 2023年 第17卷 第4期   页码 504-515 doi: 10.1007/s11708-022-0855-3

摘要： Thermal energy storage has been a pivotal technology to fill the gap between energy demands and energy supplies. As a solid-solid phase change material, shape-memory alloys (SMAs) have the inherent advantages of leakage free, no encapsulation, negligible volume variation, as well as superior energy storage properties such as high thermal conductivity (compared with ice and paraffin) and volumetric energy density, making them excellent thermal energy storage materials. Considering these characteristics, the design of the shape-memory alloy based the cold thermal energy storage system for precooling car seat application is introduced in this paper based on the proposed shape-memory alloy-based cold thermal energy storage cycle. The simulation results show that the minimum temperature of the metal boss under the seat reaches 26.2 °C at 9.85 s, which is reduced by 9.8 °C, and the energy storage efficiency of the device is 66%. The influence of initial temperature, elastocaloric materials, and the shape-memory alloy geometry scheme on the performance of car seat cold thermal energy storage devices is also discussed. Since SMAs are both solid-state refrigerants and thermal energy storage materials, hopefully the proposed concept can promote the development of more promising shape-memory alloy-based cold and hot thermal energy storage devices.

关键词： shape-memory alloy (SMA)     elastocaloric effect (eCE)     cooled seat     cold thermal energy storage    

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Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 475-483 doi: 10.1007/s11705-021-2070-x

摘要： Surface functionalization or modification to introduce more oxygen-containing functional groups to biochar is an effective strategy for tuning the physicochemical properties and promoting follow-up applications. In this study, non-thermal plasma was applied for biochar surface carving before being used in contaminant removal and energy storage applications. The results showed that even a low dose of plasma exposure could introduce a high number density of oxygen-functional groups and enhance the hydrophilicity and metal affinity of the pristine biochar. The plasma-treated biochar enabled a faster metal-adsorption rate and a 40% higher maximum adsorption capacity of heavy metal ion Pb2+. Moreover, to add more functionality to biochar surface, biochar with and without plasma pre-treatment was activated by KOH at a temperature of 800 °C. Using the same amount of KOH, the plasma treatment resulted in an activated carbon product with the larger BET surface area and pore volume. The performance of the treated activated carbon as a supercapacitor electrode was also substantially improved by>30%. This study may provide guidelines for enhancing the surface functionality and application performances of biochar using non-thermal-based techniques.

关键词： non-thermal plasma     surface functionalization     biochar modification     wastewater treatment     supercapacitor    

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Fabrication of form stable NaCl-Al2O3 composite for thermal energy storage by cold sintering process

Bilyaminu Suleiman, Qinghua Yu, Yulong Ding, Yongliang Li

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 727-735 doi: 10.1007/s11705-019-1823-2

摘要： A form stable NaCl-Al O (50-50 wt-%) composite material for high temperature thermal energy storage was fabricated by cold sintering process, a process recently applied to the densification of ceramics at low temperature ˂ 300°C under uniaxial pressure in the presence of small amount of transient liquid. The fabricated composite achieved as high as 98.65% of the theoretical density. The NaCl-Al O composite also retained the chloride salt without leakage after 30 heating-cooling cycles between 750°C–850°C together with a holding period of 24 h at 850°C. X-ray diffraction measurements indicated congruent solubility of the alumina in chloride salt, excellent compatibility of NaCl with Al O , and chemical stability at high temperature. Structural analysis by scanning electron microscope also showed limited grain growth, high density, uniform NaCl distribution and clear faceted composite structure without inter-diffusion. The latent heat storage density of 252.5 J/g was obtained from simultaneous thermal analysis. Fracture strength test showed high sintered strength around 5 GPa after 50 min. The composite was found to have fair mass losses due to volatilization. Overall, cold sintering process has the potential to be an efficient, safe and cost-effective strategy for the fabrication of high temperature thermal energy storage materials.

关键词： cold sintering process     composite fabrication     thermal energy storage     phase change materials    

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Numerical simulation of underground seasonal cold energy storage for a 10 MW solar thermal power plant

Zulkarnain ABBAS, Yong LI, Ruzhu WANG

《能源前沿（英文）》 2021年 第15卷 第2期   页码 328-344 doi: 10.1007/s11708-020-0676-1

摘要： This paper aims to explore an efficient, cost-effective, and water-saving seasonal cold energy storage technique based on borehole heat exchangers to cool the condenser water in a 10 MW solar thermal power plant. The proposed seasonal cooling mechanism is designed for the areas under typical weather conditions to utilize the low ambient temperature during the winter season and to store cold energy. The main objective of this paper is to utilize the storage unit in the peak summer months to cool the condenser water and to replace the dry cooling system. Using the simulation platform transient system simulation program (TRNSYS), the borehole thermal energy storage (BTES) system model has been developed and the dynamic capacity of the system in the charging and discharging mode of cold energy for one-year operation is studied. The typical meteorological year (TMY) data of Dunhuang, Gansu province, in north-western China, is utilized to determine the lowest ambient temperature and operation time of the system to store cold energy. The proposed seasonal cooling system is capable of enhancing the efficiency of a solar thermal power plant up to 1.54% and 2.74% in comparison with the water-cooled condenser system and air-cooled condenser system respectively. The techno-economic assessment of the proposed technique also supports its integration with the condenser unit in the solar thermal power plant. This technique has also a great potential to save the water in desert areas.

关键词： seasonal cold energy storage     borehole heat exchangers     typical meteorological data     TRNSYS     condenser cooling     techno-economic assessment    

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Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 564-576 doi: 10.1007/s11705-018-1720-0

摘要：

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power (CSP) plants as high-temperature thermal energy storage (TES) and heat transfer fluid (HTF) materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP-nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as containers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures (500–800 °C) for realizing the commercial application of molten chlorides in CSP. The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions (e.g., temperature, atmosphere). Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词： corrosion mechanisms     impurities     metallic corrosion     salt purification     electrochemical techniques    

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Optimisation for interconnected energy hub system with combined ground source heat pump and boreholethermal storage

Da HUO, Wei WEI, Simon Le BLOND

《能源前沿（英文）》 2018年 第12卷 第4期   页码 529-539 doi: 10.1007/s11708-018-0580-0

摘要： Ground source heat pumps (GSHP) give zero-carbon emission heating at a residential level. However, as the heat is discharged, the temperature of the ground drops, leading to a poorer efficiency. Borehole inter-seasonal thermal storage coupled with GSHP maintains the efficiency at a high level. To adequately utilize the high performance of combined GSHP and the borehole system to further increase system efficiency and reduce cost, such a combined heating system is incorporated into the interconnected multi-carrier system to support the heat load of a community. The borehole finite element (FE) model and an equivalent borehole transfer function are proposed and respectively applied to the optimisation to analyze the variation of GSHP performance over the entire optimisation time horizon of 24 h. The results validate the borehole transfer function, and the optimisation computation time is reduced by 17 times compared with the optimisation using the FE model.

关键词： borehole thermal storage     energy hub     ground source heat pumps (GSHP)     particle swarm optimisation    

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Thermal performance of phase change material energy storage floor for active solar water-heating system

Ruolang ZENG, Xin WANG, Wei XIAO, Yinping ZHANG, Qunli ZHANG, Hongfa DI,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 185-191 doi: 10.1007/s11708-009-0079-9

摘要： The conventional active solar water-heating floor system contains a big water tank to store energy in the day time for heating at night, which takes much building space and is very heavy. In order to reduce the water tank volume or even cancel the tank, a novel structure of an integrated water pipe floor heating system using shape-stabilized phase change materials (SSPCM) for thermal energy storage was developed and experimentally studied in this paper. The thermal performances of the floors with and without the SSPCM were compared under the intermittent heating condition. The results show that the Energy Storage Ratio (ESR) of the SSPCM floor is much higher than that of the non-SSPCM floor; the SSPCM floor heating system can provide stable heat flux and prevent a large attenuation of the floor surface temperature. Also, the SSPCM floor heating system dampens the indoor temperature swing by about 50% and increases the minimum indoor air temperature by 2°C–3°C under experimental conditions. The SSPCM floor heating system has a potential of making use of the daytime solar energy for heating at night efficiently.

关键词： phase change material     energy storage ratio     active solar water-heating    

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solar multiple on the performance of direct steam generation solar power tower plant with integrated thermalstorage

Yan LUO, Xiaoze DU, Lijun YANG, Chao XU, Muhammad AMJAD

《能源前沿（英文）》 2017年 第11卷 第4期   页码 461-471 doi: 10.1007/s11708-017-0503-5

摘要： Solar multiple (SM) and thermal storage capacity are two key design parameters for revealing the performance of direct steam generation (DSG) solar power tower plant. In the case of settled land area, SM and thermal storage capacity can be optimized to obtain the minimum levelized cost of electricity (LCOE) by adjusting the power generation output. Taking the dual-receiver DSG solar power tower plant with a given size of solar field equivalent electricity of 100 MW in Sevilla as a reference case, the minimum LCOE is 21.77 ￠/kWh with an SM of 1.7 and a thermal storage capacity of 3 h. Besides Sevilla, two other sites are also introduced to discuss the influence of annual DNI. When compared with the case of Sevilla, the minimum LCOE and optimal SM of the San Jose site change just slightly, while the minimum LCOE of the Bishop site decreases by 32.8% and the optimal SM is reduced to 1.3. The influence of the size of solar field equivalent electricity is studied as well. The minimum LCOE decreases with the size of solar field, while the optimal SM and thermal storage capacity still remain unchanged. In addition, the sensitivity of different investment in sub-system is investigated. In terms of optimal SM and thermal storage capacity, they can decrease with the cost of thermal storage system but increase with the cost of power generation unit.

关键词： direct steam generation     solar power tower     solar multiple     thermal energy storage capacity     levelized cost of electricity (LCOE)    

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Energy storage resources management: Planning, operation, and business model

《工程管理前沿（英文）》   页码 373-391 doi: 10.1007/s42524-022-0194-4

摘要： With the acceleration of supply-side renewable energy penetration rate and the increasingly diversified and complex demand-side loads, how to maintain the stable, reliable, and efficient operation of the power system has become a challenging issue requiring investigation. One of the feasible solutions is deploying the energy storage system (ESS) to integrate with the energy system to stabilize it. However, considering the costs and the input/output characteristics of ESS, both the initial configuration process and the actual operation process require efficient management. This study presents a comprehensive review of managing ESS from the perspectives of planning, operation, and business model. First of all, in terms of planning and configuration, it is investigated from capacity planning, location planning, as well as capacity and location combined planning. This process is generally the first step in deploying ESS. Then, it explores operation management of ESS from the perspectives of state assessment and operation optimization. The so-called state assessment refers to the assessment of three aspects: The state of charge (SOC), the state of health (SOH), and the remaining useful life (RUL). The operation optimization includes ESS operation strategy optimization and joint operation optimization. Finally, it discusses the business models of ESS. Traditional business models involve ancillary services and load transfer, while emerging business models include electric vehicle (EV) as energy storage and shared energy storage.

关键词： energy storage system     energy storage resources management     planning configuration     operational management     business model    

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Viability of a concentrated solar power system in a low sun belt prefecture

Rahul BHATTACHARJEE, Subhadeep BHATTACHARJEE

《能源前沿（英文）》 2020年 第14卷 第4期   页码 850-866 doi: 10.1007/s11708-020-0664-5

摘要： Concentrating solar power (CSP) is considered as a comparatively economical, more efficient, and large capacity type of renewable energy technology. However, CSP generation is found restricted only to high solar radiation belt and installed where high direct normal irradiance is available. This paper examines the viability of the adoption of the CSP system in a low sun belt region with a lower direct normal irradiance (DNI). Various critical analyses and plant economics have been evaluated with a lesser DNI state. The obtained results out of the designed system, subjected to low DNI are not found below par, but comparable to some extent with the performance results of such CSP plants at a higher DNI. The analysis indicates that incorporation of the thermal energy storage reduces the levelized cost of energy (LCOE) and augments the plant capacity factor. The capacity factor, the plant efficiency, and the LCOE are found to be 32.50%, 17.56%, and 0.1952 $/kWh, respectively.

关键词： concentrated solar power     direct normal irradiance     plant performance     plant economics     thermal energy storage    

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Load shedding scheme for an interconnected hydro-thermal hybrid system with SMES

D. TYAGI, Ashwani KUMAR, Saurabh CHANANA

《能源前沿（英文）》 2012年 第6卷 第3期   页码 227-236 doi: 10.1007/s11708-012-0198-6

摘要： The frequency of the power system varies based on the load pattern of the consumers. With continuous increase in the load, the frequency of the system keeps decreasing and may reach its minimum allowable limits. Further increase in the load will result in more frequency drop leading to the need of load shedding, if excess generation is not available to cater the need. This paper proposed a methodology in a hybrid thermal-hydro system for finding the required amount of load to be shed for setting the frequency of the system within its minimum allowable limits. The load shedding steps were obtained based on the rate of change of frequency with the increase in the load in both areas. The impact of superconducting magnetic energy storage (SMES) was obtained on load shedding scheme. The comparison of the results was presented on the two-area system.

关键词： critical load     frequency response     load shedding     multi-area system     rate of change of frequency     superconducting magnetic energy storage (SMES) device    

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标题 作者 时间 类型 操作

Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system

Weilong WANG, Yukun HU, Jinyue YAN, Jenny NYSTR?M, Erik DAHLQUIST

期刊论文

Experimental study and assessment of thermal energy storage mortar with paraffin/recycled brick powder

Luchen HAO; Jianzhuang XIAO; Wanzhi CAO; Jingting SUN

期刊论文

Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

期刊论文

A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

期刊论文

Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

期刊论文

Fabrication of form stable NaCl-Al2O3 composite for thermal energy storage by cold sintering process

Bilyaminu Suleiman, Qinghua Yu, Yulong Ding, Yongliang Li

期刊论文

Numerical simulation of underground seasonal cold energy storage for a 10 MW solar thermal power plant

Zulkarnain ABBAS, Yong LI, Ruzhu WANG

期刊论文

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

期刊论文

Optimisation for interconnected energy hub system with combined ground source heat pump and boreholethermal storage

Da HUO, Wei WEI, Simon Le BLOND

期刊论文

Thermal performance of phase change material energy storage floor for active solar water-heating system

Ruolang ZENG, Xin WANG, Wei XIAO, Yinping ZHANG, Qunli ZHANG, Hongfa DI,

期刊论文

丁玉龙：Thermal Energy Storage for a Net-Zero Energy Future — The Role, Development Status and Outlook（2021

丁玉龙(院士)

2021年07月06日

会议视频

solar multiple on the performance of direct steam generation solar power tower plant with integrated thermalstorage

Yan LUO, Xiaoze DU, Lijun YANG, Chao XU, Muhammad AMJAD

期刊论文

Energy storage resources management: Planning, operation, and business model

期刊论文

Viability of a concentrated solar power system in a low sun belt prefecture

Rahul BHATTACHARJEE, Subhadeep BHATTACHARJEE

期刊论文

Load shedding scheme for an interconnected hydro-thermal hybrid system with SMES

D. TYAGI, Ashwani KUMAR, Saurabh CHANANA

期刊论文